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Extractive
Gas Analyzers
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Model
Model 7000 Extractive IR Analyzers |
Description
The propsed Model 7000 analyzer uses non-dispersive infrared (NDIR) absorption spectroscopy for the continuous real-time measurement of on to six different gases such as CO, CO2, SO2, NO, NO2, NOx, N2O, H2O, HCI, CH4, total hydrocarbons, etc. It uses a single beam, dual wavelenght ratioing (GFC, gas filter correlation and/or DOAS differential optical absorption spectroscopy) precision gas analysis. The system incorporates a rugged but simple opto-electronic design with microprocessor based control for flexibility for a broad range of applications and reliable long term operaion. |
Measurement
CO, CO2, HCI, H2O, SO2, NO, NO2, N2O, EtO, HCOH, N |
Features
* PRIMARY BENEFITS OF EXTRACTIVE SYSTEM * PRIMARY LIMITATIONS (AS COMPARED TO IN-SITU) * EXTRACTIVE IR ANALYZER MODEL TYPES * UV ABSORPTION ANALYTICAL TECHNIQUE * EXTRACTIVE SAMPLING SYSTEM MODEL TYPES |
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Details |
| Primary Benefits of Extractive Systems
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(a) Can measure dirty streams.... Sampling allows sample preparation... removing dust from heavy particulate streams; removing water drops from wet streams; lowering gas temperature when required; etc... (b) High or Low Sensitivity .... Extractive systems can be designed for high sensitivity, by choosing an optical pathlength sufficient to meet the sensitivity requirements, by including a small volume multi-pass sample cell; (c) Elevated pressure streams....High pressure gas streams can be sampled by reducing the pressure to ambient; etc (d) Economical.... One analyzer can be multiplexed to monitor several different streams sequentially; or even several different points in the same stream; (e) Accessible.... The analytical hardware can be located at ground level for easy access, in a temperature-controlled environment, if desired. (f) System Expansion.... Can readily add other gas analyzers to the system, such as a heated FID hydrocarbons analyzer, a chemiluminescence NOx analyzer, a zirconia or paramagnetic O2 analyzer or a thermal conductivity hydrogen analyzer when these are required.
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| Primary Limitations (as compared to in-situ)
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(a) Requires sampling, with sample contact, and possible sample loss or reaction; (b) Increased system maintenance...... Must maintain the sampling system also; (c) Generally more expensive than in-situ systems; (d) Slower response, due to sample transit time. (e) Measures at a single point; may not be representative of the average composition of a stratified gas stream. (f) Requires calibration gases for frequent periodic system standardization, while the in-situ system can use EPA-Compliant internal calibration standards.
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| Extractive IR Analyzer Model Types
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Most analyzers measure samples at ambient temperatures, but some gases can condense, ie become liquids [such as H2O or certain HCs] if the temperatrure is reduced, so the sample must be measured hot. AIM offers both type of analyzers and sampling systems. See "Exhibit, AIM Model 7000 - System Description" for more details. The basic AIM models, where X = number of gases measured, are: Model 710X Ambient temperature multigas[X = 1 to 6] NDIR analyzer. Model 711X Ambient temperature single(or dual) gas NDIR analyzer. Model 720X Heated multigas [X = 1 to 6] NDIR analyzer, maintaining condensible vapors above their dew point. Model 721X Heated single (or dual) gas [X = 1 to 6] NDIR analyzer, maintaining condensible vapors above their dew point. Model 761X Ambient temp multigas DIR analyzer. Model 762X Heated multigas DIR analyzer. Model 770X Ambient temp analyzer from California Analytical. Model 771X Ambient temp Mini-CEMS from California Analytical. Model 781X Ambient temp multigas FTIR analyzer. Model 782X Heated multigas FTIR analyzer.
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| UV Absorption Analytical Technique
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What is the UV? UV is ultraviolet. UV are the wavelengths shorter than the visible.... typically from 190 nm to the visible (~400 nm). Below ~190 nm, water absorbs strongly, and below about 165 nm O2 absorbs strongly, so these wavelengths are not useable unless the analyzer operates in a vacuum.. Why do we need to use UV absorption also? Complimentary to IR absorption. (a) Only Spectral Region - Some gases absorb only in the UV, not in the IR. Examples are homonuclear diatomics such as Cl2, F2, (which we measure) as well as H2 and O2 (which we do not measure in the UV ... because O2 is such a strong UV absorber, the O2 in the air makes it impossible to measure H2 or O2 unless the system operates in a vacuum with all the air and hence O2 removed); (b) Higher Sensitivity - Some gases, such as SO2, NH3 & NO have much stronger absorption bands in the UV than in the IR, so we can measure with higher sensitivity (i.e. lower concentrations); (c) Reduce/Eliminate Interferences - In many cases, different gases may have absorption bands that overlap...for example in the IR NO absorbs at 5.3 microns (Ħ) which is in the middle of a water band, and many times we want to measure ppm levels of NO in the presence of % levels of H2O; but in the UV, many of the NO absorption lines are completely free of water interference.
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| UV Absorption Measurement Types
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(a) Single or Dual Beam DUV Absorption Spectroscopy, dual wavelength ratioing [ a UV spectrum is generated and two or more wavelengths are measured, one set where the sample uniquely absorbs light, and a second adjacent set where the sample gases do not absorb light, as a reference]; (b) Single or Dual Beam NDUV Absorption Spectroscopy, dual wavelength ratioing [two narrow bandpass filters are selected, one for a wavelength where the sample gas uniquely absorbs light, and a 2nd for an adjacent reference wavelength, where the sample gases do not absorb light; or (c) DUV (Dispersive UV) DOAS, where a spectrum between 200 and 500nm is generated with the array detector spectrometer, the background subtracted, the measured absorption features correlated with known reference spectra in memory; and weak signals extracted from the backgound with a proprietary partial least squares singular value decomposition pattern recognition software.
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| UV Absorption Analyzer Model Types
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Extractive multigas, DUV.... Model 510X (ambient temp) and 520X (heated), X=1 to 10+ Extractive single gas, NDUV.... Model 511Y (ambient temp) and 521Y (heated), Y=1 or 2 In-Situ multigas,DUV.... Model 560X with an E-6000 optical projection system, or Model 565X with an on-stream optical projection system & optical fiber connection to a remote analyzer. Open-Path Ambient Air DUV.... Model 580X Remote Vehicle Exhaust DUV.. Model 585X
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| Limitations Of In-Situ Installations
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Same as E-6000 NDIR system, but in addition, the in-situ across-stream UV system can not be used after a wet scrubber with water drops present, under any conditions; and the particulate levels must be below 100 mg/Nm3 max. |
| Limitations of Extractive Systems
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UV mirrors do not reflect light as efficiently as IR mirrors, so the number of passes in a multi-pass sample cell is limited. A typical maximum cell length is 10m. |
| UV Absoprtion Measurement Ranges
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The sensitivity is higher than for the IR. Typical MMR (minimum full-scale ranges) are.... NO = 5 ppm.m, SO2 = 2 ppm.m, NH3 = 5 ppm.m; with a 2% of MMR detection limit for 1 min response time, and 0.7% of MMR for 10 min response time. |
| Extractive Sampling System Model Types: [Applicable to IR and UV Process Analyzers]
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AIM Model numbers and Descriptions: Model 7501..... ambient temperature sampling system, where the sample temperature is reduced to ambient, and the measurement is at ambient temp. [Since most samples contain levels of water that would condense at ambient temperatures, the water must be removed. This technique is often called ¡§cold, dry¡¨]. Model 7502..... heated sampling system, where the sample is kept hot, by heating all system components that it comes in contact with, including the analyzer sample cell. In this way the water does not condense. [This technique is often called ¡§hot, wet¡¨]. Model 7503.... dilution-based sampling system, where the sample is continuously diluted with a precise known volume of clean dry air to lower the sample temperature close to ambient, and to dilute the sample below the dew point so that water and other condensibles do not condense. Multiplexed..... Model # - Y, where Y= the number of sample points being sequentially monitored. [One analyzer can be time shared between several sampling points, to reduce system cost; (but at the same time this reduces the system response time, and may result in the analyzer not measuring the specific stream at the moment of a process upset)]. In addition a new system is now becoming available. This is a hybrid system with an on-stream projection system [like the E-6000 analyzer] so there is no sample extraction from the process, coupled to a remote analyzer (typically separated from the projection system, on the ground, or on the platform for easier access) by a fiber-optic bundle. These fibers are generally available for measurements between 230nm in the UV and the near IR (to 2 microns).
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More products/models on
extractive gas analyzers...
| Description |
Information |
| Name/Model No |
Model 7000 Extractive IR Analyzers |
| Brief Description |
The propsed Model 7000 analyzer uses non-dispersive infrared (NDIR) absorption spectroscopy for the continuous real-time measurement of on to six different gases such as ..... |
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